Here is a quick guide for PowerShell tips in SharePoint 2010: http://www.powergui.org/servlet/KbServlet/download/2812-102-4534/SharePoint2010PowerShell.pdf And this Technet article gives a complete mapping of STSADM commands with PowerShell Commands: http://technet.microsoft.com/en-us/library/ff621081.aspx
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